PFA (Perfluoroalkoxy Alkane) is a high-performance fluoropolymer with unique chemical and physical properties.
PFA (Perfluoroalkoxy Alkane) is a high-performance fluoropolymer with unique chemical and physical properties.
PFA (Perfluoroalkoxy Alkane) is a high-performance fluoropolymer with unique chemical and physical properties. The following is a detailed introduction to its preparation method and properties:
1. Preparation method of PFA
1. **Raw materials**:
PFA is a copolymer of tetrafluoroethylene (TFE) and perfluoroalkyl vinyl ether (such as perfluoropropyl vinyl ether, PPVE). By adjusting the content of PPVE (typically 1-10%), its melt flowability and crystallinity can be controlled.
2. Polymerization process:
Emulsion polymerization: In an aqueous phase, suspended polymer particles are formed through a catalytic reaction involving fluorinated surfactants and initiators such as ammonium persulfate.
Solution polymerization: It is carried out in organic solvents, requiring strict control of temperature and pressure.
Post-treatment: After polymerization, the finished product is obtained through washing, drying, granulation, and other steps.
PFA (Perfluoroalkoxy Alkane) is a high-performance fluoropolymer with unique chemical and physical properties. The following is a detailed introduction to its preparation method and properties:
1. Preparation method of PFA
1. **Raw materials**:
PFA is a copolymer of tetrafluoroethylene (TFE) and perfluoroalkyl vinyl ether (such as perfluoropropyl vinyl ether, PPVE). By adjusting the content of PPVE (usually 1-10%), its melt flowability and crystallinity can be controlled.
2. Polymerization process:
Emulsion polymerization: In an aqueous phase, catalyzed by fluorinated surfactants and initiators (such as ammonium persulfate), a reaction occurs to generate suspended polymer particles.
Solution polymerization: It is carried out in organic solvents, and strict control of temperature and pressure is required.
Post-treatment: After polymerization, the finished product is obtained through washing, drying, granulation, and other steps.
3. Key points:
The introduction of the comonomer PPVE disrupts the regular structure of PTFE, rendering it melt processable.
High-purity raw materials are required to avoid side reactions, and process conditions (such as temperature and pressure) directly affect the molecular weight distribution.
II. Performance characteristics of PFA
1. Chemical properties:
Corrosion resistance: It is resistant to strong acids (such as concentrated sulfuric acid, aqua regia), strong alkalis, organic solvents, and oxidants, second only to PTFE.
Inertness: Physiological inertness, suitable for use in the medical device and semiconductor industries.
2. Physical properties:
Temperature range: -200°C to +260°C for long-term use, with short-term exposure up to 300°C.
Electrical properties: Low dielectric constant (2.1) and small dissipation factor, suitable for high-frequency circuit insulation.
Mechanical properties: Tensile strength of approximately 28-31 MPa, elongation of 300%, superior to the brittleness of PTFE.
3. Processing characteristics:
Melt flowability: The melting point is approximately 305°C, and it can be processed using thermoplastic processes such as injection molding and extrusion.
Surface characteristics: extremely low friction coefficient (0.05-0.08), non-stick, hydrophobic and oleophobic.
4. Optical performance:
- High transparency (visible light transmittance > 90%), suitable for optical windows or observation windows in corrosive environments.
III. Typical applications of PFA
Semiconductor: High-purity chemical delivery pipelines, wafer carriers (resistant to plasma erosion).
Chemical industry: lined valves, pump bodies, and seals (as substitutes for fiberglass and metal).
Medical: catheters, bioreactor components (autoclavable).
Wire and cable: Insulation layer for aerospace cables (flame retardant, resistant to extreme temperatures).
Product parameters
| Outer diameter * Inner diameter(mm) OD xID | maximum length(m) max length | Outer diameter * Inner diameter(mm) OD xID | maximum length(m) max length | ||||||||||||||||||||||
| φ2*φ1.6 | 300 | φ16*13 | 50 | ||||||||||||||||||||||
| φ3*φ2.2 | 250 | φ16*φ14 | 50 | ||||||||||||||||||||||
| φ4*φ3.2 | 200 | φ20*φ16 | 50 | ||||||||||||||||||||||
| φ5*φ4 | 200 | φ20*φ18 | 50 | ||||||||||||||||||||||
| φ6*φ3 | 200 | φ25*φ21 | 50 | ||||||||||||||||||||||
| φ6*φ4 | 200 | φ25*φ22 | 50 | ||||||||||||||||||||||
| φ6*φ5 | 200 | φ32*φ28 | 6 | ||||||||||||||||||||||
| φ8*6 | 100 | φ32*φ29 | 6 | ||||||||||||||||||||||
| φ8*φ7 | 100 | φ36*32 | 6 | ||||||||||||||||||||||
| φ10*φ7 | 100 | φ36*30 | 6 | ||||||||||||||||||||||
| φ10*8 | 100 | φ40*34 | 6 | ||||||||||||||||||||||
| φ10*φ9 | 100 | φ40*φ36 | 6 | ||||||||||||||||||||||
| φ12*φ10 | 100 | φ50*φ46 | 6 | ||||||||||||||||||||||
| φ12*φ11 | 100 | φ60*φ54 | 6 | ||||||||||||||||||||||
| φ16*12 | 100 | φ80*φ70 | 6 | ||||||||||||||||||||||